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Chemical Kinetics

Chemical Kinetics

by Harsh Gupta -
Number of replies: 1

Q - The inversion of cane sugar proceeds with a constant half life of 500 minutes at pH = 5 for any concentration of sugar when pH is changed to 4, the half life becomes 50 minutes. Deduce the rate law expression for inversion of sugar.

In reply to Harsh Gupta

Re: Chemical Kinetics

by Krishnan G -

Since half life is constant at a given pH, it is first order with respect to sucrose. if concentration of H+  increases by 10 times, half life decreases by 10 times. so it is second order with respect to H+.

So the rate law is R = [Sucrose] [H+]2