Problems 26-30
(30) What is the e.m.f. of a cell at room temperature containing two hydrogen electrodes, the negative one in contact with 10-6 M OH- ions and the positive one in contact with 0.05 M H+?
Submission: Closed
Solution provided by Jithin edited by INDIANET :
It is a concentration cell as both the electrodes are made of hydrogen.
\(E_{cell}=\frac {0.059}{n}log \frac {c_1}{c_2}\); (at room temperature)
n = 1;
c1= 0.05 M .......(Given that cathode has 0.05 concentration of H+ which is the positive side)
The ionic product of water = Kw = 10-14 = [
or, 10-6x [H+] = 10-14;
Therefore, c2= [H+]= 10-14/10-6=10-8M;
\(E_{cell}=\frac {0.059}{1}log \frac {0.05}{10^{-8}}\)
=0.059log(5x106)
=0.059 x 6.6989
=0.3952V
Cracked by:
- Aman Verma, Hans Raj Model School, Punjabi Bagh, New Delhi.
- Jithin Prakash, 12, Army School, Deolali.
(29) a, b, c are sides of a triangle, then prove that
.
Submission: Closed
Solution (.pdf) provided by Jathin
Cracked by:
- Umang Merwana, Bhopal (M.P.).
- Jathin Das, Class XII, Abu Dhabi Indian School, Abu Dhabi, UAE.
(28) Evaluate:
Where [ ] denotes the greatest integer function.
Submission: Closed
Solution Provided by Nachiket:
We shall first prove one general result (A)
\(S=[x]+[x+\frac{1}{n}]+[x+\frac{2}{n}]+............+[x+\frac{n-1}{n}]=[nx]\)
Proof::
Let p be the first number for which \([x+\frac{p}{n}]=[x]+1\)
So {x} i.e. fractional part of x =\(\frac{n-p}{n}\) + (a number less than 1/n)
Also, [x +(n-1/n)]<=[x]+1
As n-1/n is a fraction less than 1
So [x]+....[x+(p-1/n)]=p[x]
& [x+p/n] +...+[x+(n-1/n)]=(n-p)[x]+(n-p)
Hence S=n[x]+(n-p).......(1)
Now n{x}=n* (n-p/n) +n*( a number less than 1/n)
= n-p + a number less than 1 ........(2)
Hence [nx]=[ n[x] + n{x} ] =[ n[x] + n-p + a number less than 1 ] from (2)
=n[x] +(n-p) ........................(3)
Hence proved from (2) & (3)
Now returning to the given problem From result (A) the fraction in problem is transformed to
Z={[x] +[2x] +......+[nx]}/n^2
We know that x-1<[x] < x+1
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Similarly nx-1<[nx]<nx+1
So Adding All these terms and dividing each side by n^2 we get
{(x-1)+....(nx-1)}/n^2<Z<{(x+1)+....(nx+1)}/n^2
So{ x(1+...+n)-n(1)} /n^2<Z<{ x(1+...+n)+n(1)} /n^2
So x(n )(n+1)/2 n^2 -1/n<Z< x(n )(n+1)/2 n^2 +1/n
So x/2+(x-2/2n)< Z< x/2+(x+2/2n)
Taking limit on both sides as n-->infinity we get
X/2<= Required Limit <= x/2
Hence By Sandwich Theorem We Get The Required Limit = x/2
Cracked by:
Nachiket Vaidya, 12th, Sathaye College, Vile Parle, Mumbai.
(27)
Submission: Closed
Cracked by:
- Yash Agrawal, Bhopal (M.P.).
- Jithin Prakash, 12, Army School, Deolali.
(26)
Submission: Closed
Answer: .
Cracked by:
- Umang Merwana, Bhopal (M.P.).
- TusharJain, Babu Banarsidas Institute of Technology, Gaziabad, U.P.
- Yash Agrawal, Bhopal (M.P.).