Represent the surface area, volume using similar terms and also using the semi-vertical angle.
Differentiate to get the required value. The question is very simple and can be easily. Give it a try again, you will surely be able to solve it.
problem from maxima and minima
differentiate v=1/3 pi r2h taking h= l2 - r2
dv/dr=0
therefore l=3r;therefore sine of semivertical angle = r/l
=r/3r
=1/3